Taking the policy of electric vehicle users responding to peak and valley time price into account, the decision to change the electric vehicle charging scheme makes the electric vehicle disordered charging into a planned and predictable orderly charge. On this basis, the impact of different responsiveness of peak to valley TOU price on reconfiguration of distribution network is discussed in this paper. A mathematical model based on the minimum cost of reconfiguration cost of distribution network is established, and the hybrid particle swarm and ant colony algorithm is applied to solve the model. The IEEE33 node system is simulated to verify the validity of the proposed method in the solution of distribution network reconfiguration. Secondly, it is proved that the transfer of charging in the electric vehicle to the electricity price valley time period can effectively reduce the cost loss of the distribution network reconfiguration, the higher the user response degree, the loss of reconfiguration cost of distribution network is less.